3 diols with pyruvate esters. Initial efforts in screening for catalyst suitable for the decomposition of the diazoacetoacetates resulted in the novel synthesis of the Barceloneic lactone derivatives in respectable yields. Further efforts led to the preparation of the achiral rhodium (II) heptafluorobutyramide which proved successful for the decomposition of the vinyldiazoketones to give the bicyclic acetals in moderate yields. Video on ASMR Videos and Their Ability to Relieve Stress ASMR
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